FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRIC STUDY OF A PARAMAGNETIC PLATINUM OLIGOMER WITH GUANINE

Authors
VOLCHENSKOVA II SHALIMOV SA KEISEVICH LV POKROVSKII VA KOPYTIN SN
Citation
Ii. Volchenskova et al., FAST-ATOM-BOMBARDMENT MASS-SPECTROMETRIC STUDY OF A PARAMAGNETIC PLATINUM OLIGOMER WITH GUANINE, Journal of structural chemistry, 35(4), 1994, pp. 528-532
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
35
Issue
4
Year of publication
1994
Pages
528 - 532
Database
ISI
SICI code
0022-4766(1994)35:4<528:FMSOAP>2.0.ZU;2-W
Abstract
The mass-spectrometric behavior of a paramagnetic platinum oligomer wi th guanine was determined by the fast atom bombardment method. The com plex is built of PtCl2 groups linked by guanine molecules into a chain via the imidazole N7 atom and the exocyclic OC6 atom. In a dimethylsu lfoxide solution, the degree of oligomerization of the complex is n = 4.