Transition metal borides are used for the reinforcement of B4C-based c
eramics after densification by hot pressing or hot-isostatic pressing.
The study of the growth mechanism of well faceted W2B5 platelets is p
resented. The in-situ grown W2B5 phase shows a characteristic anisotro
pic crystal growth with a distinct subgrain structure. The spontaneou
cleavage behaviour of this crystal is discussed with respect to strain
s in the crystal structure.