The behaviour of Kr atoms implanted into aluminium at room temperature
with a dose of 1 x 10(15) Kr/cm(2) has been investigated by a channel
ling method for isochronal annealing up to 683 K. In the as-implanted
state the Kr atoms are distributed over tetrahedral (T), octahedral (O
), substitutional (S) and random (R) sites. On annealing at 433 and 59
3 K, the T- and O-site occupancies disappear, respectively, and in bot
h cases the fraction of the S-site occupancy decreases and that of the
R-site occupancy increases. The T- and O-site occupancies have been i
nterpreted to be a result of the formation of Kr-vacancy (V) complexes
of KrV4 and KrV6, respectively, and the R-site occupancy to be Kr ato
ms associated with cavities. Therefore, the annealing stages at 433 an
d 593 K are explained in terms of the dissociation of KrV4 and KrV6, r
espectively. On annealing at 683 K, solid krypton is formed.