M. Kandlikar et Gj. Mcrae, INVERSION OF THE GLOBAL METHANE CYCLE USING CHANCE-CONSTRAINED PROGRAMMING - METHODOLOGY AND RESULTS, Chemosphere, 30(6), 1995, pp. 1151-1170
This paper presents a new methodology for constraining sources and sin
ks in mass balances and applies it to a global model of methane. Sourc
es and sinks are treated as random variables that are constrained by i
sotopic mass balance and ice-core data. A chance constrained programmi
ng formulation is used to perform inverse calculations and determine c
onstrained bounds on sources of methane. Budgets consistent with atmos
pheric concentrations, flux measurements, and priors on model variable
s and parameters are derived. It is observed that global budgets of me
thane presented in the literature have greater uncertainty ranges than
allowed by the constraints on its global cycle. The analysis shows th
at emissions from rice paddies and wetlands may be lower than presente
d in previous budgets, a result that is in agreement with recent estim
ates based on flux measurements. Ranges for other anthropogenic source
s such as biomass burning, and fossil and landfill emissions are also
obtained. Sensitivity analysis is used to determine the key uncertain
parameters in the global methane budget.