M. Giona et al., CONVECTION-DIFFUSION TRANSPORT IN DISORDERED STRUCTURES - NUMERICAL-ANALYSIS BASED ON THE EXIT-TIME EQUATION, Chemical Engineering Science, 50(6), 1995, pp. 1001-1011
The problem of biased diffusion in disordered media (percolation clust
ers) is analysed by means of the exit-time equation. Numerical simulat
ions show that for percolation lattices tending to criticality, the vo
lume-averaged exit time as a function of the Peclet number, Pe, deviat
es from the regular 1/Pe-behaviour and for high Pe grows monotonically
with Pe. Numerical simulations on DLA-clusters and deterministic frac
tals indicate the applicability of the exit-time approach to singular
fractal structures. Finally, exit-time analysis is adopted in explaini
ng standard and non-standard features of dispersion of solute particle
s in highly heterogeneous porous packings.