SYNTHESIS AND PROPERTIES OF COPOLYMERS CONSISTING OF ARAMIDE AND POLY(6-HEXANELACTAM) BLOCKS

Authors
MAREK M STEHLICEK J DOSKOCILOVA D
Citation
M. Marek et al., SYNTHESIS AND PROPERTIES OF COPOLYMERS CONSISTING OF ARAMIDE AND POLY(6-HEXANELACTAM) BLOCKS, European Polymer Journal, 31(4), 1995, pp. 363-368
Citations number
20
Categorie Soggetti
Polymer Sciences
Journal title
European Polymer Journal → ACNP
ISSN journal
00143057
Volume
31
Issue
4
Year of publication
1995
Pages
363 - 368
Database
ISI
SICI code
0014-3057(1995)31:4<363:SAPOCC>2.0.ZU;2-O
Abstract
Low molecular weight aromatic polyamides of the meta-type which bear N -acyl-6-hexanelactam end-groups were prepared, characterized by NMR an d utilized as initiators of the anionic polymerization of 6-hexanelact am. The resulting block copolymers poly(6-hexanelactam)-block-poly(iso phthalic -1,3-phenylenediamine)-block-poly-(6-hexanelactam) were chara cterized by NMR, DSC, TGA, X-ray diffraction and microscopy of solutio n-cast films and compared with an aramide-polyamide 6 blend also prepa red by polymerization.