SILVER-PROMOTED CONVERSION OF CYCLOPROPENE TO ALLYLIC PRODUCTS

Authors
MCKENNA MC KIM RJ MCKENNA CE
Citation
Mc. Mckenna et al., SILVER-PROMOTED CONVERSION OF CYCLOPROPENE TO ALLYLIC PRODUCTS, Tetrahedron letters, 36(13), 1995, pp. 2223-2226
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
13
Year of publication
1995
Pages
2223 - 2226
Database
ISI
SICI code
0040-4039(1995)36:13<2223:SCOCTA>2.0.ZU;2-B
Abstract
Cyclopropene 1, passed in a He stream through a gas chromatography col umn containing firebrick impregnated with a saturated solution of AgNO 3 in glycerol, reacted to give acrolein 6 (6%) and allyl nitrate 7 (20 %). The products were identified by GC, MS,IR, and H-1 NMR. A mechanis m is proposed to explain the reactions.