PORPHYRINS AND AZAPORPHINES AS CATALYSTS IN ALKENE EPOXIDATIONS WITH PERACETIC-ACID

Authors
BANFI S MONTANARI F QUICI S BARKANOVA SV KALIYA OL KOPRANENKOV VN LUKYANETS EA
Citation
S. Banfi et al., PORPHYRINS AND AZAPORPHINES AS CATALYSTS IN ALKENE EPOXIDATIONS WITH PERACETIC-ACID, Tetrahedron letters, 36(13), 1995, pp. 2317-2320
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
13
Year of publication
1995
Pages
2317 - 2320
Database
ISI
SICI code
0040-4039(1995)36:13<2317:PAAACI>2.0.ZU;2-V
Abstract
the reactivities of five Mn-III(Cl) - porphinoids were compared in the catalytic alkene epoxidations in CH3CN solution with peracetic acid a s primary oxidant Porphyrins 1 and 2 bearing Cl and NO2 substituents s howed the best efficiency while tetraazaporphyrin 5 was found to bean interesting catalyst for terminal alkene epoxidations.