LARGE 3RD-ORDER OPTICAL NONLINEARITIES IN TRANSITION-METAL OXIDES

ADVANCES in the field of optical computing(1-3) will require the devel opment of materials that combine a large nonlinear optical response wi th a fast response time. For many applications, this translates into a third-order nonlinear optical susceptibility, chi((3)), in excess of 10(-8) e.s.u., and a response time faster than 10 ps (ref. 4). Althoug h a wide range of inorganic and organic(19-21) materials have been fou nd to exhibit a large chi((3)) either the response times tend to be fa r too slow or the materials are not sufficiently stable for device app lications. Recently, the transition-metal oxide Fe2O3 was found to hav e a large chi((3)) (ref. 22). Here we show that oxides of several othe r 3d transition metals show a similarly large nonlinear optical respon se; moreover, we find that a significant contribution to the overall c hi((3)) (similar to 10(-8) e.s.u. in the case of V2O5) has a response time of the order of 35 ps.