PALLADIUM-CATALYZED COUPLING OF HETEROAROMATIC TRIFLATES WITH ACETYLENE AND ITS APPLICATION FOR A DYNEMICIN-A INTERMEDIATE

Authors
OKITA T ISOBE M
Citation
T. Okita et M. Isobe, PALLADIUM-CATALYZED COUPLING OF HETEROAROMATIC TRIFLATES WITH ACETYLENE AND ITS APPLICATION FOR A DYNEMICIN-A INTERMEDIATE, Tetrahedron, 51(13), 1995, pp. 3737-3744
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
13
Year of publication
1995
Pages
3737 - 3744
Database
ISI
SICI code
0040-4020(1995)51:13<3737:PCOHTW>2.0.ZU;2-3
Abstract
An acetylene moiety was introduced to a carbonyl carbon of amide group via its triflate in the presence of palladium catalyst, The reaction proceeded smoothly under mild conditions. Utilizing this methodology, a model compound of dynemicin A bearing acetylene group was synthesize d.