SELECTIVE HETEROGENEOUS EPOXIDATIONS WITH CP-TITANIUM CHLORIDE DERIVED MICROPOROUS SILICA GLASSES

Authors
THORIMBERT S KLEIN S MAIER WF
Citation
S. Thorimbert et al., SELECTIVE HETEROGENEOUS EPOXIDATIONS WITH CP-TITANIUM CHLORIDE DERIVED MICROPOROUS SILICA GLASSES, Tetrahedron, 51(13), 1995, pp. 3787-3792
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
13
Year of publication
1995
Pages
3787 - 3792
Database
ISI
SICI code
0040-4020(1995)51:13<3787:SHEWCC>2.0.ZU;2-C
Abstract
A new heterogeneous epoxidation catalyst is prepared by the copolycond ensation of cyclopentadienyl titanium chlorides with tetraethoxysilane by a modified sol-gel procedure. Epoxidations of non-activated olefin s in the presence of these new heterogeneous catalysts are described.