L. Brzozka et al., SYNTHESES WITH AROMATIC NITRAMINES .9. HALOGENATION OF 2-NITRAMINOPYRIDINE AND 4-NITRAMINOPYRIDINE, Polish Journal of Chemistry, 69(4), 1995, pp. 605-611
Isomeric 2- and 4-nitraminopyridines (free acids and anions) were subj
ected to halogenation (iodination, bromination and chlorination). The
iodination of nitraminopyridine anions failed, and the bromination and
chlorination led selectively to 5-monohalogenated products independen
tly of whether free acids or anions of nitraminopyridines were reacted
.