B. Paci et al., NEUTRON-SCATTERING DETERMINATION OF THE CRYSTAL-FIELD PARAMETERS IN ERCU4AL8 AND ERFE4AL8 INTERMETALLICS, Solid state communications, 94(6), 1995, pp. 489-493
An inelastic neutron scattering experiment has been performed in order
to determine the crystal field potential acting at the rare earth sit
e in the paramagnetic phase of ErCu4Al8 and ErFe4Al8 intermetallic com
pounds. The profile refinement of the spectra measured at different te
mperatures, and experimental information on the electric field gradien
t available in the literature, allow a reliable estimate of the parame
ters for the tetragonal crystal field. Positive values of the lowest o
rder term B2(0) suggest an easy plane magnetic anisotropy of the Er su
blattice, but the higher order terms could play an important role in d
etermining the magnetisation direction.