MONTE-CARLO SIMULATION OF COMPLEX ISOMERIZATION .2. EFFECT OF ADSORPTION ON PRODUCT SELECTIVITY

Authors
WANG JG LI YW CHEN SY PENG SY
Citation
Jg. Wang et al., MONTE-CARLO SIMULATION OF COMPLEX ISOMERIZATION .2. EFFECT OF ADSORPTION ON PRODUCT SELECTIVITY, Reaction kinetics and catalysis letters, 54(1), 1995, pp. 65-71
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
54
Issue
1
Year of publication
1995
Pages
65 - 71
Database
ISI
SICI code
0133-1736(1995)54:1<65:MSOCI.>2.0.ZU;2-Z
Abstract
The complex isomerization A=B=C over zeolite catalysts was simulated b y the Monte Carlo method, and the effect of adsorption of molecules ac companied with chemical reaction upon the product selectivity has been investigated. The results show that the product selectivity is clearl y related to the difference of equilibrium adsorption constants of mol ecules in the reaction. This suggests that the shape selectivity in ze olite-catalyzed reactions is the result of the channel structure and s urface acidity of zeolite catalysts.