Rg. Gerritse, THE EFFECTS OF FLOW-RATE AND DISTANCE TRAVELED ON THE MOBILITY OF PHOSPHATE IN SOILS, Transport in porous media, 16(3), 1994, pp. 237-251
Effects of flow rate and distance travelled on average mobilities of p
hosphate in a soil are estimated from breakthrough curves of phosphate
at the outlets of small columns of soil, following step increases in
the concentration at the inlets. Experimental results are compared wit
h results from a computer simulation model of leached columns of soil.
Average mobilities of phosphate in columns of soil, following a step
increase in the input concentration, decrease with decreasing rate of
flow and with increasing distance travelled and appear to be linearly
correlated on a logarithmic scale with both flow rate and distance tra
velled. An empirical equation, describing these relationships, is fitt
ed to data from leaching experiments at flow rates between 30 and 600
cm/day in approximate to 10 cm long columns of soil. Coefficients are
obtained by curve fitting breakthrough curves, calculated with a numer
ical computer simulation model, to experimental breakthrough curves. T
he fitted equation enables extrapolation to flow rates and travel dist
ances that are more relevant to a field situation.