A DIRECT METHOD FOR THE SYNTHESIS OF POLYFUNCTIONALIZED UNSATURATED CARBONYL DERIVATIVES BY MICHAEL ADDITION OF NITROALKANES TO ENEDIONES WITH THE HELP OF DBU

Authors
BALLINI R BOSICA G
Citation
R. Ballini et G. Bosica, A DIRECT METHOD FOR THE SYNTHESIS OF POLYFUNCTIONALIZED UNSATURATED CARBONYL DERIVATIVES BY MICHAEL ADDITION OF NITROALKANES TO ENEDIONES WITH THE HELP OF DBU, Tetrahedron, 51(14), 1995, pp. 4213-4222
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
14
Year of publication
1995
Pages
4213 - 4222
Database
ISI
SICI code
0040-4020(1995)51:14<4213:ADMFTS>2.0.ZU;2-7
Abstract
The Michael addition of several nitroalkanes to dimethyl maleate, (Z)- 3-hexene-2,5-dione, N-ethyl maleimide, and N-phenyl maleimide, in MeCN or THF, proceeds very efficiently on DBU as base, and furnishes good to high yields of polyfunctionalized or saturated carbonyl derivatives .