PYRROLE-2-DITHIOCARBOXYLATES - SYNTHESIS OF 2-(1-ALKYLTHIO-2-CYANOETHENYL)PYRROLES

Citation
Ln. Sobenina et al., PYRROLE-2-DITHIOCARBOXYLATES - SYNTHESIS OF 2-(1-ALKYLTHIO-2-CYANOETHENYL)PYRROLES, Tetrahedron, 51(14), 1995, pp. 4223-4230
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404020
Volume
51
Issue
14
Year of publication
1995
Pages
4223 - 4230
Database
ISI
SICI code
0040-4020(1995)51:14<4223:P-SO2>2.0.ZU;2-#
Abstract
2-(1-Alkylthio-2-cyanoethenyl)pyrroles were synthesized in good to hig h yields by reaction of pyrrole-2-dithiocarboxylates with active methy lene nitriles in a KOH-DMSO medium. The condensation of 4,5,6,7-tetrah ydroindole with cyanoacetate also leads to ,5,6,7-tetrahydrocyclohexa- [c]-3H-pyrrolizin-3-one in 61% yield. The effect of substituent on the reaction course has been studied. The dipole moments and spectral cha racteristics of products are presented.