M. Ylihalla et Rh. Loeppert, ZINC ADSORPTION BY MINERAL SOILS OF FINLAND, Acta agriculturae Scandinavica. Section B, Soil and plant science, 45(1), 1995, pp. 15-21
Zinc adsorption by 10 (pH 4.0-6.5) cultivated mineral soils from Finla
nd was studied in batch experiments. Additions of Zn ranged up to 600
mg kg-1 of soil and the corresponding equilibrium concentrations were
0.1-13 mg l-1. In each soil, Zn adsorption conformed to the Freundlich
isotherm. Despite a relatively low initial Zn adsorption by the acidi
c soils, each of the soils proved to have a high potential to adsorb Z
n, but the capacity was highly pH dependent. In addition to the conven
tional Freundlich adsorption isotherms, calculated separately for each
soil, extended Freundlich-type isotherms that also incorporate soil p
H and other soil characteristics were used to describe Zn adsorption o
f several soils simultaneously in one equation. The pH-dependent Freun
dlich adsorption isotherm proved to serve as a practical tool to asses
s Zn adsorption by soils varying in pH and other characteristics.