THE EFFECT OF AN ILLUMINATION JUMP ON WAVE-PROPAGATION IN THE RU-CATALYZED BELOUSOV-ZHABOTINSKY REACTION

Citation
Mkr. Reddy et al., THE EFFECT OF AN ILLUMINATION JUMP ON WAVE-PROPAGATION IN THE RU-CATALYZED BELOUSOV-ZHABOTINSKY REACTION, Chemical physics letters, 236(1-2), 1995, pp. 111-116
Citations number
18
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
236
Issue
1-2
Year of publication
1995
Pages
111 - 116
Database
ISI
SICI code
0009-2614(1995)236:1-2<111:TEOAIJ>2.0.ZU;2-I
Abstract
The influence of visible light on the trigger wave propagation in a th in layer of the Ru(bpy)3(2+) -catalyzed Belousov-Zhabotinsky reaction is investigated. The velocity evolution of a wave propagating in the d ark was followed after switching on the light. The velocity starts to decrease immediately, but a new stationary value is attained only afte r about 10 s. The inhibitory effect on the propagation velocity was mo re pronounced in thin reactive layers than in thick ones. The experime ntal data were compared with computational results obtained with a mod ified Oregonator model.