L. Lozzi et al., EXFAS STUDIES ON THE THERMAL-BEHAVIOR OF COPPER SURFACE, Journal of electron spectroscopy and related phenomena, 72, 1995, pp. 223-227
The crystalline structure of copper surface has been studied by means
of the Extended Fine Auger Structure spectroscopy as a function of the
sample temperature. The oscillating features observed beyond the Cu M
2,3VV Auger transition, due to an autoionization process involving the
3p and d-valence band electrons, have been analysed following the Ext
ended X-ray Absorption Fine Structure theory, when the sample temperat
ure grows from 300 K to 900 K. As the temperature increases no shift o
f the nearest neighbour distances but a sizeable increase of the Debye
-Waller factor have been observed. The results show the capability of
the EXFAS technique to follow the thermal behaviour of the surface str
ucture of solids with higher surface sensitivity than other electronic
spectroscopies.