S. Fritzsche, ANGULAR-DISTRIBUTION IN THE 1S-]3P COHERENTLY EXCITED RESONANT KLL AUGER SPECTRUM IN NEON, Journal of electron spectroscopy and related phenomena, 72, 1995, pp. 249-254
Angular anisotropies, energies, and relative intensities have been stu
died for the 1s --> 3p resonant KLL spectrum in neon. The resonant exc
itation of the 1s2p(2)2p(6)3p configuration leads to a multiplet of fo
ur levels with J = 0, 1, 2, and an energy splitting less-than-or-equal
-to 35 meV which is much smaller than the natural level widths of abou
t 250 meV. Thus, the various states of the multiplet are excited (more
or less) coherently. To obtain the angular distribution of the Auger
lines, knowledge of the density matrix is required. This matrix includ
es all information about the specific excitation process, whereas the
dynamics of the autoionization is described by the relative intensitie
s and Auger angular parameters A2. Multiconfiguration Dirac-Fock wave
functions have been used to calculate this set of coefficients in an i
ntermediate coupling scheme including initial and final state correlat
ions. The use of these data in the interpretation of an angular distri
bution measurement is briefly discussed.