TETRACYANOETHYLENE-INDUCED CHLORINATIVE CLEAVAGE OF PERMETHYLATED OLIGOGERMANES WITH POLYHALOMETHANES

Authors
MOCHIDA K HATA R HODOTA C FUKUZUMI S KAKO M NAKADAIRA Y
Citation
K. Mochida et al., TETRACYANOETHYLENE-INDUCED CHLORINATIVE CLEAVAGE OF PERMETHYLATED OLIGOGERMANES WITH POLYHALOMETHANES, Chemistry Letters, (3), 1995, pp. 245-245
Citations number
2
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
3
Year of publication
1995
Pages
245 - 245
Database
ISI
SICI code
0366-7022(1995):3<245:TCCOPO>2.0.ZU;2-G
Abstract
In the presence of tetracyanoethylene (TCNE), Ge-Ge bonds of oligogerm anes (Me(Me(2)Ge)(n)Me, n=2-5) were cleaved with CCl4 to yield the cor responding chlorogermanes. A mechanism involving an oligogermane radic al cation is proposed for the Ge-Ge cleavage.