PERFLUOROALKYLQUINONES - SYNTHESIS USING BIS(PERFLUOROALKANOYL) PEROXIDES, ABSORPTION-BANDS, AND SOLUBILITY

Authors
MATSUI M KONDOH S SHIBATA K MURAMATSU H
Citation
M. Matsui et al., PERFLUOROALKYLQUINONES - SYNTHESIS USING BIS(PERFLUOROALKANOYL) PEROXIDES, ABSORPTION-BANDS, AND SOLUBILITY, Bulletin of the Chemical Society of Japan, 68(3), 1995, pp. 1042-1051
Citations number
36
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Chemical Society of Japan → ACNP
ISSN journal
00092673
Volume
68
Issue
3
Year of publication
1995
Pages
1042 - 1051
Database
ISI
SICI code
0009-2673(1995)68:3<1042:P-SUBP>2.0.ZU;2-P
Abstract
The reactions of 1,4-benzo-, naphtho-, and 9,10-anthraquinones with bi s(perfluoroalkanoyl) peroxides gave the corresponding perfluoroalkylat ed derivatives. Those of 2-methyl- and 2-[4-(chloroanilino)]-1,4-napht hoquinones with bis(oxaperfluoroalkanoyl) peroxides afforded the dichl oromethyl and trifluoromethyl derivatives, respectively. Absorption ba nds of the perfluoroalkylated naphtho- and anthraquinone dyes showed a slight hypsochromic shift. The solubilities of the perfluoroalkylated anthraquinone dyes into hexane were much more higher than those of th e non-perfluoroalkylated ones.