RACEMIC AND DIASTEREOSELECTIVE SYNTHESIS OF ALKYL(1,3-BUTADIEN-2-YL)METHANOLS VIA A NOVEL HOMOALLENYLBORATION OF ALDEHYDES WITH DIISOPROPYL2,3-BUTADIEN-1-YLBORONATE

Authors
SOUNDARARAJAN R LI GS BROWN HC
Citation
R. Soundararajan et al., RACEMIC AND DIASTEREOSELECTIVE SYNTHESIS OF ALKYL(1,3-BUTADIEN-2-YL)METHANOLS VIA A NOVEL HOMOALLENYLBORATION OF ALDEHYDES WITH DIISOPROPYL2,3-BUTADIEN-1-YLBORONATE, Tetrahedron letters, 36(14), 1995, pp. 2441-2444
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
14
Year of publication
1995
Pages
2441 - 2444
Database
ISI
SICI code
0040-4039(1995)36:14<2441:RADSOA>2.0.ZU;2-E
Abstract
Diisopropyl 2,3-butadien-1-ylboronate has been prepared by a simple me thod and its utility as a novel homoallenylborating reagent has been d emonstrated with a series of aldehydes. Also, a high diastereoselectiv ity of this reagent in its reaction with an alpha-chiral aldehyde has been established.