CARBON-CARBON BOND FORMATION WITH NEW MITSUNOBU REAGENTS

Authors
TSUNODA T NAGAKU M NAGINO C KAWAMURA Y OZAKI F HIOKI H ITO S
Citation
T. Tsunoda et al., CARBON-CARBON BOND FORMATION WITH NEW MITSUNOBU REAGENTS, Tetrahedron letters, 36(14), 1995, pp. 2531-2534
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
14
Year of publication
1995
Pages
2531 - 2534
Database
ISI
SICI code
0040-4039(1995)36:14<2531:CBFWNM>2.0.ZU;2-G
Abstract
The efficiency of three azodicarboxylic acid derivatives and a stabili zed phosphorane in the Mitsunobu type C-C bond formation was compared utilizing the reactions of three nucleophiles of different pK(a)'s and several alcohols of different structure types. The study established the characteristics of each reagent. The synthesis of two insect phero mone analogs was accomplished effectively using these homologation rea ctions.