CRYSTAL-STRUCTURE OF THE (ET)(8)[HG4BR12-CENTER-DOT(PHCL)(2)] ORGANICMETAL AND THE (ET)(8)[HG4BR12-CENTER-DOT(MEPHCL)(2)] ORGANIC SEMICONDUCTOR - THE PRODUCTS OF THE SAME SYNTHESIS
Oa. Dyachenko et al., CRYSTAL-STRUCTURE OF THE (ET)(8)[HG4BR12-CENTER-DOT(PHCL)(2)] ORGANICMETAL AND THE (ET)(8)[HG4BR12-CENTER-DOT(MEPHCL)(2)] ORGANIC SEMICONDUCTOR - THE PRODUCTS OF THE SAME SYNTHESIS, Synthetic metals, 70(1-3), 1995, pp. 801-802
X-ray study of the cation-radical salts (ET)(8)[Hg4Br12.(PhCl)(2)] (me
tal up to 90 K) and (ET)(8)[Hg4Br12.(MePhCl)(2)] (semiconductor) prepa
rated in the same synthesis has shown considerable differences in the
structures of their cationic and anionic layers. It is these differenc
es that account for different electrophysical properties of these comp
ounds.