D. Chasseau et al., PRESSURE AND TEMPERATURE-DEPENDENCE OF THE STRUCTURAL-PROPERTIES OF THE MOLECULAR SEMICONDUCTING SALT - ALPHA'-(BEDT-TTF)(2)AG(CN)(2), Synthetic metals, 70(1-3), 1995, pp. 945-946
The temperature and pressure dependence of the electrical conductivity
of the alpha'-(BEDT-TTF)(2)Ag(CN)(2) salt shows a transition between
two semiconducting phases at a critical temperature depending on press
ure. This transition is crystallographically characterized by the appe
arance of a superstructure corresponding to the doubling of the b para
meter. We present and discuss here the parameters evolution at decreas
ing temperature and increasing pressure and the structural evolution u
nder constraints.