KNIGHT-SHIFT AND SPIN-DENSITY CALCULATIONS IN X-DITHIOLATE-PERYLENE CONDUCTORS (X=AU, PD, PT)

Authors
FIRLEJ L ZAHAB A BERNIER P
Citation
L. Firlej et al., KNIGHT-SHIFT AND SPIN-DENSITY CALCULATIONS IN X-DITHIOLATE-PERYLENE CONDUCTORS (X=AU, PD, PT), Synthetic metals, 70(1-3), 1995, pp. 1097-1098
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
70
Issue
1-3
Year of publication
1995
Pages
1097 - 1098
Database
ISI
SICI code
0379-6779(1995)70:1-3<1097:KASCIX>2.0.ZU;2-9
Abstract
Solid state high resolution C-13 NMR investigations of 3 isostructural organic conductors, Per(2)X(mnt)(2) (Per-perylene, X=Pd, Pt and Au) a re reported. The observed metallic shifts of resonances are interprete d as due to the Pauli paramagnetism of conducting electrons of perylen e chains only and are in agreement with inhomogeneous spin density dis tribution over perylene cation resulting from Huckel calculations.