ELECTRON-SPIN-RESONANCE STUDIES OF CHEMICALLY AND ELECTROCHEMICALLY GENERATED C-60 AND (CH3)(2)C-60 MONOANIONS

Authors
JONES MT KADISH KM SUBRAMANIAN R BOULAS P VIJAYASHREE MN
Citation
Mt. Jones et al., ELECTRON-SPIN-RESONANCE STUDIES OF CHEMICALLY AND ELECTROCHEMICALLY GENERATED C-60 AND (CH3)(2)C-60 MONOANIONS, Synthetic metals, 70(1-3), 1995, pp. 1341-1342
Citations number
15
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
70
Issue
1-3
Year of publication
1995
Pages
1341 - 1342
Database
ISI
SICI code
0379-6779(1995)70:1-3<1341:ESOCAE>2.0.ZU;2-B
Abstract
Electron spin resonance (ESR) data on several chemically generated C-6 0(-) Salts as well as electrochemically generated (CH3)2C(60)(-) are p resented. The g values for a series of tetraalkylammonium, pyridinium, phosphonium and arsonium salts are independent of the identity of the cation whereas their linewidth varies from 10.0 to 53.6 G. The anion of (CH3)2C(60)(-) has a g value of 2.000 and an ESR linewidth of 2.8 G , typical of a system containing a non-degenerate LUMO.