L. Gustavsson et B. Leckner, ABATEMENT OF N2O EMISSIONS FROM CIRCULATING FLUIDIZED-BED COMBUSTION THROUGH AFTERBURNING, Industrial & engineering chemistry research, 34(4), 1995, pp. 1419-1427
A method for the abatement of N2O emission from fluidized bed combusti
on has been investigated. The method consists of burning a secondary f
uel after the normal circulating fluidized bed combustor. Liquefied pe
troleum gas (LPG), fuel oil, pulverized coal, and wood, as well as saw
dust, were used as the secondary fuel. Experiments showed that the N2O
emission can be reduced by 90% or more by this technique. The resulti
ng N2O emission was principally a function of the gas temperature achi
eved in the afterburner and independent of afterburning fuel, but the
amount of air in the combustion gases from the primary combustion also
influences the results. No negative effects on sulfur capture or on N
O or CO emissions were recorded. In the experiments, the primary cyclo
ne of the fluidized bed boiler was used for afterburning. If afterburn
ing is implemented in a plant optimized for this purpose, an amount of
secondary fuel corresponding to 10% of the total energy input should
remove practically all N2O. During the present experiments the seconda
ry fuel consumption was greater than 10% of the total energy input due
to various losses.