THE SEARCH FOR THE ETHYNYL CATION - NITROSATION OF N,N-BIS (TRIMETHYLSILYL)YNAMINES

Citation
Rm. Alvarez et al., THE SEARCH FOR THE ETHYNYL CATION - NITROSATION OF N,N-BIS (TRIMETHYLSILYL)YNAMINES, Journal of physical organic chemistry, 8(3), 1995, pp. 191-194
Citations number
14
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
ISSN journal
08943230
Volume
8
Issue
3
Year of publication
1995
Pages
191 - 194
Database
ISI
SICI code
0894-3230(1995)8:3<191:TSFTEC>2.0.ZU;2-0
Abstract
The reaction of bis-silylated ynamines with different nitrosyl reagent s affords products derived from an electrophilic attack at the beta-ca rbon atom and not the expected alkynyldiazonium salts.