PALLADIUM-CATALYZED CARBONYL ALLYLATION OF ALDEHYDES BY ALLYLIC CYCLIC CARBONATES

Authors
KANG SK PARK DC PARK CH JANG SB
Citation
Sk. Kang et al., PALLADIUM-CATALYZED CARBONYL ALLYLATION OF ALDEHYDES BY ALLYLIC CYCLIC CARBONATES, Synthetic communications, 25(9), 1995, pp. 1359-1366
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
9
Year of publication
1995
Pages
1359 - 1366
Database
ISI
SICI code
0039-7911(1995)25:9<1359:PCAOAB>2.0.ZU;2-#
Abstract
Palladium(O)-catalyzed allylation of aldehydes by allylic cyclic carbo nates with SnCl2 proceeded smoothly to afford 1,3-diols with high dias tereocontrol. For the exomethylene cyclic carbonate, allylation with a ldehydes furnished 1,4-diols or 1,5-diols depending on amount of aldeh ydes.