The paper studies the composition and the structure of the chemical sp
ecies (sublates) isolated in scum, in the process of Ni(II) ion(collig
end) separation by iono-molecular flotation from diluted solutions usi
ng laurylamine (LA) as collector. The chemical analysis data correlate
d with molecular electrical conductivity measurements, electronic and
vibrational spectra, TD analysis and X Rays spectra of sublates establ
ish the coordinative nature of collector-colligend interaction The Ni(
II) recovery as NiO can be done by the calcination of sublates at 500
degrees, 1/2 hour.