REACTION OF KETENES WITH 3 MEMBERED HETEROCYCLIC RINGS .1. ADDITION OF TERT-BUTYL-CYANOKETENE AND CHLOROCYANOKETENE TO ISOBUTYLENEOXIDE - ANEW ENE-LIKE REACTION

Authors
DANILA MG GOTTLIEB H BARTOS A FILIP P
Citation
Mg. Danila et al., REACTION OF KETENES WITH 3 MEMBERED HETEROCYCLIC RINGS .1. ADDITION OF TERT-BUTYL-CYANOKETENE AND CHLOROCYANOKETENE TO ISOBUTYLENEOXIDE - ANEW ENE-LIKE REACTION, Revue Roumaine de Chimie, 39(10), 1994, pp. 1223-1228
Citations number
23
Categorie Soggetti
Chemistry
Journal title
Revue Roumaine de Chimie → ACNP
ISSN journal
00353930
Volume
39
Issue
10
Year of publication
1994
Pages
1223 - 1228
Database
ISI
SICI code
0035-3930(1994)39:10<1223:ROKW3M>2.0.ZU;2-M
Abstract
A new type of addition products in the reaction of cyano-substituted k etenes with alkyl-oxiranes is reported. The formation of methylallylic esters of the ketenes corresponding acids is explained by an ''ene''- like reaction, with ketene as ''enophile'' and tile C-O bond of the ox irane playing the role of the ''ene'' double bond.