Correlation could be observed between the structure of the inhibitor m
olecule and inhibition efficiency, A newly introduced phosphono group
was found to increase the anticorrosion activity. The differences in t
he complex forming properties of phosphonic and carboxylic acids are d
ue to the differences in basicity, charge, electron-donating effect an
d size of phosphono and carboxyl groups, Correlation was found between
the complex forming behaviour and inhibiting efficiency of organic co
mpounds, Efficiency results obtained for the same inhibitors by two di
fferent methods showed good correlation without the use of metal ions.