STRUCTURAL ORDER IN MCM-41 CONTROLLED BY SHIFTING SILICATE POLYMERIZATION EQUILIBRIUM

Authors
RYOO R KIM JM
Citation
R. Ryoo et Jm. Kim, STRUCTURAL ORDER IN MCM-41 CONTROLLED BY SHIFTING SILICATE POLYMERIZATION EQUILIBRIUM, Journal of the Chemical Society, Chemical Communications, (7), 1995, pp. 711-712
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1995
Pages
711 - 712
Database
ISI
SICI code
0022-4936(1995):7<711:SOIMCB>2.0.ZU;2-I
Abstract
Powder X-ray diffraction, Si-29 and Xe-129 NMR spectroscopy of MCM-41 show that the long-range structural order and textural uniformity of t he mesoporous molecular sieve are markedly improved due to a shift in the reaction equilibrium when acetic acid is repeatedly added during t he conversion of sodium silicate and NMe(3)(C16H33)Cl to a MCM-41 phas e.