ORGANOIMIDO LIGANDS WITH REMOTE FUNCTIONALITY - A P-PYRIDYLIMIDO COMPLEX OF VANADIUM(V) AND ITS USE AS A METALLOLIGAND

Authors
HILL PL YAP GPA RHEINGOLD AL MAATTA EA
Citation
Pl. Hill et al., ORGANOIMIDO LIGANDS WITH REMOTE FUNCTIONALITY - A P-PYRIDYLIMIDO COMPLEX OF VANADIUM(V) AND ITS USE AS A METALLOLIGAND, Journal of the Chemical Society, Chemical Communications, (7), 1995, pp. 737-738
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1995
Pages
737 - 738
Database
ISI
SICI code
0022-4936(1995):7<737:OLWRF->2.0.ZU;2-N
Abstract
The exposed nitrogen atom of the p-pyridylimido ligand in the vanadium (v) species [(N3N)V=N-C5H4N] 1 {N3N = [(Me(3)SiNCH(2)CH(2))(3)N](3-)} provides a reactive site capable of complexing a second metal fragment , enabling the construction of new types of heterobimetallic complexes linked by a compact conjugated bridge.