SYNTHESIS OF THE FIRST TRITHIOCARBONATOGOLD COMPLEX - [N(PPH(3))(2)](2)[AU-2(MU(2)-ETA(2)-CS3)(2)] - FIRST CRYSTAL-STRUCTURE OF A MU(2)-ETA(2)-BRIDGING TRITHIOCARBONATO COMPLEX

Authors
VICENTE J CHICOTE MT GONZALEZHERRERO P JONES PG
Citation
J. Vicente et al., SYNTHESIS OF THE FIRST TRITHIOCARBONATOGOLD COMPLEX - [N(PPH(3))(2)](2)[AU-2(MU(2)-ETA(2)-CS3)(2)] - FIRST CRYSTAL-STRUCTURE OF A MU(2)-ETA(2)-BRIDGING TRITHIOCARBONATO COMPLEX, Journal of the Chemical Society, Chemical Communications, (7), 1995, pp. 745-746
Citations number
49
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
7
Year of publication
1995
Pages
745 - 746
Database
ISI
SICI code
0022-4936(1995):7<745:SOTFTC>2.0.ZU;2-W
Abstract
The reaction of [N(PPh(3))(2)][Au(SH)(2)] with CS2 gives [N(PPh(3))(2) ](2)[AU(2)(mu(2)-eta(2)-CS3)(2)] whose crystal structure shows planar [AU(2)(mu(2)-eta(2)-CS3)(2)](2-) anions and two [N(PPh(3))(2)] cations ; the coordination at gold is almost linear [SAuS 172.80(5)degrees] an d both gold atoms are doubly bridged by CS3 anions, associated with a very short Au ... Au contact of 2.7998(4) Angstrom.