M. Kishida et al., NOVEL PREPARATION OF METAL-SUPPORTED CATALYSTS BY COLLOIDAL MICROPARTICLES IN A WATER-IN-OIL MICROEMULSION - CATALYTIC-HYDROGENATION OF CARBON-DIOXIDE, Journal of the Chemical Society, Chemical Communications, (7), 1995, pp. 763-764
A novel catalyst preparation method of employing microemulsions, and t
he carbon dioxide hydrogenation activities of silica- or zirconia-supp
orted catalysts loaded with colloidal rhodium microparticles in water-
in-oil microemulsions are reported; the catalysts thus prepared exhibi
t much higher activity than those prepared by classical methods.