Ta. Kwa et al., ANISOTROPICALLY ETCHED SILICON MIRRORS FOR OPTICAL SENSOR APPLICATIONS, Journal of the Electrochemical Society, 142(4), 1995, pp. 1226-1233
Optical devices in silicon often require mirror-quality surfaces. Memb
ranes etched in KOH using the electrochemically controlled etch (ECE)
stop have been found to have sidewalls less smooth than expected from
the (111) etch-bordering planes. Furthermore, the membrane surfaces we
re also not as smooth as could be expected from the wafer surface qual
ity before epitaxial growth, despite the use of the ECE stop. The infl
uence of the concentration and temperature of the KOH solution on the
roughness of both membrane and sidewalls has been investigated. The co
ncentration of the KOH solution was varied between 5 and 50 weight per
cent, and the temperature between 30 and 100 degrees C. It was found t
hat the membrane surface quality is highly dependent on the initial su
rface condition and the solution conditions, while the sidewall surfac
e quality is primarily dependent on the oxygen content of the wafer an
d the thermal budget due to the integration of active bipolar devices
in the epilayer prior to etching in KOH. A number of measures to be ta
ken before, during, and after the etching for improving the membrane a
s well as the sidewall surface smoothness are presented. Under the bes
t conditions, the etched surfaces had a roughness of less than 0.1 mu
m peak to peak.