A CCD camera and computer data acquisition system is used for surface
investigation by means of the reflection high energy electron diffract
ion (RHEED) method. Accuracy of these measurements, especially of latt
ice parameter determination, is limited by camera spatial distortion,
high noise, and diffraction-spot broadening. In order to resolve this
problem a detection method of a virtual camera subpixel detector is pr
oposed. The conversion function between a real camera and a perfect vi
rtual pinhole model camera is established using a method of reference
calibrate grid. The RHEED intensity diffraction patterns are approxima
ted by analytical functions which fit the simple diffraction intensity
profiles well. Then the centres of the diffraction lines and points a
re calculated with high (subpixel) precision. The accuracy of the meth
od is demonstrated by analysis of RHEED diffraction patterns obtained
from a Pd(111) surface. It is shown that the error of determination of
the diffraction spot position is lower than 0.4%. The use of the meth
od is shown for the example of Pd epitaxial film growth on a NaCl subs
trate where increased vertical lattice parameters are found.