H. Dashti et H. Albazaz, COMPARATIVE-STUDY OF THE HYDROTHERMAL STABILITY AND PERFORMANCE OF Y-ZEOLITE BASED FCC CATALYSTS HAVING DIFFERENT INITIAL SI AL RATIO/, Fuel science & technology international, 13(4), 1995, pp. 451-466
The effect of steaming temperature on the structural characteristics (
e.g. unit cell size, crystallinity and Si/Al ratio), surface area, and
acidity as well as on performance of two Y-zeolite based FCC catalyst
s (coded A and B) having different initial Si/Al ratio was investigate
d and compared. The feedstock used was vacuum gas oil from Kuwait Nati
onal Petroleum Co. (KNPC). The results of the study showed that cataly
st B with a higher initial Si/Al ratio is better than catalyst A in te
rms of retaining unit cell size and acidity under hydrothermal conditi
ons. Performance test in a microreactor (MAT) revealed that catalyst B
was more active for overall conversion. However, catalyst A was more
selective for gasoline yield and RON. It also produced less gas and co
ke yields than catalyst B.