BETA-CARBOLINE ALKALOIDS .8. REGIOSELECTIVE HOMOLYTIC ACETYLATION OF BETA-CARBOLINES

Authors
Citation
F. Bracher et J. Daab, BETA-CARBOLINE ALKALOIDS .8. REGIOSELECTIVE HOMOLYTIC ACETYLATION OF BETA-CARBOLINES, Synthetic communications, 25(10), 1995, pp. 1557-1562
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
25
Issue
10
Year of publication
1995
Pages
1557 - 1562
Database
ISI
SICI code
0039-7911(1995)25:10<1557:BA.RHA>2.0.ZU;2-X
Abstract
Homolytic acetylation of 3-ethoxycarbonyl-beta-carboline and norharman e occurs selectively at 1-position. Better yields are obtained by gene ration of the acetyl radical from acetaldehyde than by oxidative decar boxylation of pyruvic acid.