STUDIES ON GLYCOSIDES .14. STEREOSELECTIVITY AND REACTIVITY OF NEW C1LEAVING GROUP TRICHLOROACETOXYL IN GLYCOSYLATION REACTION

Authors
MAO JM CHEN HM ZHANG JI CAI MS
Citation
Jm. Mao et al., STUDIES ON GLYCOSIDES .14. STEREOSELECTIVITY AND REACTIVITY OF NEW C1LEAVING GROUP TRICHLOROACETOXYL IN GLYCOSYLATION REACTION, Synthetic communications, 25(10), 1995, pp. 1563-1565
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
10
Year of publication
1995
Pages
1563 - 1565
Database
ISI
SICI code
0039-7911(1995)25:10<1563:SOG.SA>2.0.ZU;2-V
Abstract
2,3,4,6-O-Tetrabenzyl-1-alpha-D-galactopyransyl trichloroacete (2) rea cted with a series of nucleophiles in the presence of BF3 . OEt(2) or TMSOTf to give O-, S-galactopyranosides and galactopyranosyl carboxyla tes stereoselectively in high yields.