1-NORBORNYLLITHIUM AS A PRECURSOR FOR THE SYNTHESIS OF NOVEL ORGANIC 1-BICYCLO[2.2.1]HEPTANE DERIVATIVES AND FOR THE IMPROVED PREPARATION OF 1-CHLORO-BICYCLO[2.2.2]OCTANE

Authors
KOSTOVA K DIMITROV V
Citation
K. Kostova et V. Dimitrov, 1-NORBORNYLLITHIUM AS A PRECURSOR FOR THE SYNTHESIS OF NOVEL ORGANIC 1-BICYCLO[2.2.1]HEPTANE DERIVATIVES AND FOR THE IMPROVED PREPARATION OF 1-CHLORO-BICYCLO[2.2.2]OCTANE, Synthetic communications, 25(10), 1995, pp. 1575-1587
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
25
Issue
10
Year of publication
1995
Pages
1575 - 1587
Database
ISI
SICI code
0039-7911(1995)25:10<1575:1AAPFT>2.0.ZU;2-G
Abstract
An improved strategy for synthesis of 1-chloro-bicyclo[2.2.2]octane is described in which the key compounds 1-norbornyl substituted ethyl fo rmate (3) or 1-norbornylcarbaldehyde (7) were prepared from 1-norborny llithium (1). The latter appeared as a useful precursor for the synthe sis of various organic bridgehead substituted derivatives.