D,H-MU-ALKOXOALKYLPHOSPHONATO-E-MU-ALKOXO -F-MU-OXO-BIS[TRICHLOROANTIMONY(V)] COMPOUNDS

Authors
SAUVIGNY A FAERBER JE RIHM A THURN H SCHMIDT A
Citation
A. Sauvigny et al., D,H-MU-ALKOXOALKYLPHOSPHONATO-E-MU-ALKOXO -F-MU-OXO-BIS[TRICHLOROANTIMONY(V)] COMPOUNDS, Zeitschrift fur anorganische und allgemeine Chemie, 621(4), 1995, pp. 640-644
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
4
Year of publication
1995
Pages
640 - 644
Database
ISI
SICI code
0044-2313(1995)621:4<640:D->2.0.ZU;2-F
Abstract
The binuclear antimony(V) complexes Cl3Sb(O) [R(3)(R(1)O)PO2](OR(2))Sb Cl3 1 to 7 with R(1), R(2) and R(3) = Me or Et in solution slowly exch anges the R(2) groups between the equatorial oxygen atoms of the Sb2O2 ring. The SbO(3)PO(3)Sb ringsystem makes rapid pseudorotation. The re sulting isomeres are detected by nmr spectroscopy.