THE INFLUENCE OF WATER ON THE SULFIDATION OF CONAY STUDIED BY MOSSBAUER EMISSION-SPECTROSCOPY, EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE ANDTHIOPHENE HDS ACTIVITY

Authors
DEBONT PW VISSENBERG MJ BOELLAARD E VANSANTEN RA DEBEER VHJ VANDERKRAAN AM
Citation
Pw. Debont et al., THE INFLUENCE OF WATER ON THE SULFIDATION OF CONAY STUDIED BY MOSSBAUER EMISSION-SPECTROSCOPY, EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE ANDTHIOPHENE HDS ACTIVITY, Bulletin des Societes chimiques belges, 104(4-5), 1995, pp. 205-211
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
104
Issue
4-5
Year of publication
1995
Pages
205 - 211
Database
ISI
SICI code
0037-9646(1995)104:4-5<205:TIOWOT>2.0.ZU;2-X
Abstract
The influence of physisorbed water on the sulfidation of an ion exchan ged CoNaY catalyst is studied by Mossbauer Emission Spectroscopy, Exte nded X-ray Absorption Fine Structure and Hydrodesulfurization activity measurements. Physisorbed water present during sulfidation affects th e Co-sulfide dispersion and the initial HDS activity. Its removal prio r to sulfidation clearly results in an improvement of these two cataly st parameters.