Rl. Pavlov et al., SPIN-DENSITY FUNCTIONAL THEORY .4. THE EN ERGY FUNCTIONAL FOR SPIN MANIFOLDS - POTENTIAL-ENERGY - TOTAL FUNCTIONAL, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 320(6), 1995, pp. 303-308
We pursue our application of the the local-scale transformation (LST)
to expressing the energy functional for the spin multiplicities of a m
ultifermionic system. In a previous Note we have studied the dependenc
e of the kinetic energy terms upon the choice of the model wave functi
on (MWF). In the present Note we investigate the Coulomb potential ter
ms (nucleus-electron attraction, electron-electron repulsion and inter
electronic exchange) for space or spin degenerate or non-degenerate st
ates. We analyze the components of these terms, especially the contrib
ution of the latter to the exchange correlation function. This helps u
nderstand how the scalar function of the LST determines the correlatio
n effects in the total energy.