NEW GRAPHITE-INTERCALATION COMPOUNDS C4KO2 AND C8KO2

Citation
Vz. Mordkovich et al., NEW GRAPHITE-INTERCALATION COMPOUNDS C4KO2 AND C8KO2, Synthetic metals, 71(1-3), 1995, pp. 1767-1768
Citations number
7
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
ISSN journal
03796779
Volume
71
Issue
1-3
Year of publication
1995
Pages
1767 - 1768
Database
ISI
SICI code
0379-6779(1995)71:1-3<1767:NGCCAC>2.0.ZU;2-0
Abstract
New graphite intercalation compounds were obtained by intercalation of potassium superoxide KO2 into graphite in presence of potassium metal . Stage 1 (assigned formula C4KO2, I-c = 8.44 Angstrom) and stage 2 (a ssigned formula C8KO2, I-c = 11.75 Angstrom) compounds were isolated. Quadruple intercalate layer K-O-O-K is supposed. The results of magnet ic susceptibility measurements suggest nonmagnetic states of oxygen sp ecies. Metal-like temperature dependence of c-axis resistivity was obt ained in 1.5-300 K range where the resisitivity values at room tempera ture are 0.07 Omega cm and 0.81 Omega cm for C4KO2 and C8KO2, respecti vely.