STRUCTURAL CONTROL OF QUASI-ONE-DIMENSIONAL HALOGEN-BRIDGED NICKEL-COMPLEXES

Authors
INOUE K YAMASHITA M FURUTA T ICHIKAWA A OHISHI T OKAMOTO H KIMURA N OHKI H IKEDA R BANDOW S TORIUMI K MITANI T KITAGAWA H MIYAMAE H
Citation
K. Inoue et al., STRUCTURAL CONTROL OF QUASI-ONE-DIMENSIONAL HALOGEN-BRIDGED NICKEL-COMPLEXES, Synthetic metals, 71(1-3), 1995, pp. 1913-1914
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Metallurgy & Metallurigical Engineering
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
71
Issue
1-3
Year of publication
1995
Pages
1913 - 1914
Database
ISI
SICI code
0379-6779(1995)71:1-3<1913:SCOQHN>2.0.ZU;2-4
Abstract
Several new compounds Ni(chxn)2XY2 (chxn=1R,2R-diaminocyclohexane; X=C l,Br; Y=X,NO3,ClO4BF4) were synthesized and their lattice constants we re determined by X-ray powder patterns. In these nickel complexes, the inter-chain distance in the direction of counterions depends on ion i c radius of the counterion, while the distances between metals along t he chain are nearly constant. Such results are in contrast to those of the platinum and the palladium complexes.